岩浆型铜镍硫化物矿床地质概念模型   总被引：4，自引：1，他引：4  

胡旺亮 《地球科学》1991,16(3):249-256

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辉石巨晶中的硫化物及其成因   总被引：8，自引：1，他引：8  

黄婉康  A.R.Basu 《矿物学报》1987,(2)

我国一些地区玄武岩辉石巨晶中的硫化物球泡(0.02-0.05mm)呈点阵式、散布式、定向带状或微裂隙羽状分布。硫化矿物组合是磁黄铁矿-镍黄铁矿-黄铜矿,其中以磁黄铁矿为主(～90％)。根据硫化物的规则排布以及高温矿物组合推测点阵式、散布式硫化物形成于地幔。是由溶解了～1％S的硅酸盐熔体在减压上升过程中析出过饱和的硫所致。  相似文献   

金在地幔矿物中的赋存形式及其赋存介质转化的可能模式:以中国北方一些地幔橄榄岩包体为例   总被引：1，自引：0，他引：1  

张维萍  赫英  董振信 《地球化学》2007,36(4):419-424

采集中国北方玄武岩中橄榄岩包体样品21件。测定了其中的主元素、微量元素、稀土元素(REE)和Au等的含量。橄榄岩包体中的Au含量与CaO含量的相关性表明,其中的Au可能主要赋存于单斜辉石中,反映Au含量可能与地幔演化及熔融程度有关;橄榄岩包体后期受地幔流体交代作用的影响,Au转而以硫化物形式存在,这一过程是在橄榄岩包体原有Au的物质基础上进行的。  相似文献   

含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究(英文)   总被引：4，自引：0，他引：4  

李楚思  Edward M.Ripley 《地学前缘》2007,14(5):177-185

镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。  相似文献   

PGE fractionation in seafloor hydrothermal systems: examples from mafic- and ultramafic-hosted hydrothermal fields at the slow-spreading Mid-Atlantic Ridge     

Jan Pašava  Anna Vymazalová  Sven Petersen 《Mineralium Deposita》2007,42(4):423-431

The distribution of platinum group elements (PGEs) in massive sulfides and hematite–magnetite±pyrite assemblages from the recently discovered basalt-hosted Turtle Pits hydrothermal field and in massive sulfides from the ultramafic-hosted Logatchev vent field both on the Mid-Atlantic Ridge was studied and compared to that from selected ancient volcanic-hosted massive sulfide (VHMS) deposits. Cu-rich samples from black smoker chimneys of both vent fields are enriched in Pd and Rh (Pd up to 227 ppb and Rh up to 149 ppb) when compared to hematite–magnetite-rich samples from Turtle Pits (Pd up to 10 ppb, Rh up to 1.9 ppb). A significant positive correlation was established between Cu and Rh in sulfide samples from Turtle Pits. PGE chondrite-normalized patterns (with a positive Rh anomaly and Pd and Au enrichment), Pd/Pt and Pd/Au ratios close to global MORB, and high values of Pd/Ir and Pt/Ir ratios indicate mafic source rock and seawater involvement in the hydrothermal system at Turtle Pits. Similarly shaped PGE chondrite-normalized patterns and high values of Pd/Pt and Pd/Ir ratios in Cu-rich sulfides at Logatchev likely reflect a similar mechanism of PGE enrichment but with involvement of ultramafic source rocks.  相似文献   

闽西南地区块状硫化物矿床的喷流-沉积成矿作用     

郑志强  林东燕 《福建地质》2007,26(4):222-228

通过对闽西南地区石炭纪—早二叠世主要块状硫化物矿床的区域成矿背景、贮矿层位特征以及矿石矿物成分、结构构造,硫同位素地球化学特征、成矿温度等分析研究,指出该地区石炭纪—早二叠世块状硫化物矿床的形成多与海底火山活动有关,贮矿层中伴有典型的喷流沉积岩—硅质岩,并提出闽西南地区块状硫化物矿床存在海底喷流-沉积成矿作用的新认识。  相似文献   

水体中硫化物测定方法探讨   总被引：1，自引：0，他引：1       下载免费PDF全文

刘洪林  于志强  吴启鲁  徐红蔚 《水科学进展》2002,13(2):211-214

通过对测定硫化物标准曲线的质量保证及不同污染程度水样的前处理方法的探讨,得出硫化物标准溶液需现用现配及针对污染程度不同的水样分别采取直接测定、抽滤测定和酸化-吹气法测定的结论.  相似文献   

福建省尤溪峰岩铅锌银资源潜力及找矿方向探讨   总被引：4，自引：0，他引：4  

吴建设  黄仁生 《中国地质》2001,28(12):13-18

福建尤溪峰岩铅锌银矿床产于龙北溪组(Pt2-3l)绿片岩中,成矿构造环境为大陆古裂谷,矿床成因类型属块状硫化物矿床。通过一年多的资源调查评价(地质大调查项目)工作,地质找矿取得了重大进展,已控制的铅锌银资源量均达大型规模,预测该区具有寻找超大型矿床的潜力。该矿床的解剖对于福建北部、西部及相邻的浙江南部寻找同类型矿床具有指导意义。  相似文献   

硫化物矿物溶解度与溶液pH值的关系   总被引：2，自引：0，他引：2  

贾建业  兰斌明  谢先德  吴大清  汤艳杰  王燕  王建成 《吉林大学学报(地球科学版)》2001,31(3):241-246

硫化物作为自然界常见的一大类矿物 ,由于溶解度很小 ,硫化物对水pH值的影响以及水对它的溶解度影响往往被人们所忽视。通过计算常见硫化物矿物的自由能ΔG0f、溶度积Ksp和溶解度S、绘制logS—pH曲线 ,得出硫化物矿物在不同 pH值条件下的溶解规律 ,水溶液的pH值受硫化物矿物的控制 ;反过来 ,水溶液的pH值也影响着矿物溶解度的大小。此外 ,对硫化物矿物饱和溶液的缓冲范围、缓冲容量和硫化物与溶液pH值相互作用的机理进行了探讨  相似文献   

Petrochemical Investigation of the Antique Ophiolite (Philippines): Implications on Volcanogenic Massive Sulfide and Podiform Chromitite Deposits   总被引：5，自引：0，他引：5  

Rodolfo A. TAMAYO Jr    Graciano P. YUMUL Jr    René C. MAURY  Mireille POLVÉ  Joseph COTTEN  Marcel BOHN 《Resource Geology》2001,51(2):145-164

Abstract: The Antique ophiolite, located in Panay island (west‐central Philippines), corresponds to several tectonic slices within the suture zone between the Philippine Mobile Belt (PMB) and the North Palawan Block (NPB). It includes dismembered fragments of a basaltic sequence, dominantly pillow‐lavas with minor sheet flows, rare exposures of sheeted dikes, isotropic gabbros, subordinate layered mafic and ultramafic rock sequences and serpentinites. Most of the ophiolite units commonly occur as clasts and blocks within the serpentinites, which intrude the whole ophiolitic body, as well as, the basal conglomerate of the overlying Middle Miocene sedimentary formation. The volcanic rock sequence is characterized by chemical compositions ranging from transitional (T)‐MORB, normal (N)‐MORB and to chemistry intermediate between those of MORB and island arc basalt (IAB). The residual upper mantle sequence is harzburgitic and generally more depleted than the upper mantle underlying modern mid‐oceanic ridges. Calculations using whole‐rock and mineral compositions show that they can represent the residue of a fertile mantle source, which have undergone degrees of partial melting ranging from 9‐22.5 %. Some of the mantle samples display chondrite‐nor‐malized REE and extended multi‐element patterns suggesting enrichments in LREE, Rb, Sr and Zr, which are comparable to those found in fore‐arc peridotites from the Izu‐Bonin‐Mariana (IBM) arc system. The Antique ultramafic rocks also record relatively oxidizing mantle conditions (Δlog f_O2 (FMQ)=0.9‐3.5). As a whole, the ophiolite probably represents an agglomeration of oceanic ridge and fore‐arc crust fragments, which were juxtaposed during the Miocene collision of the PMB and the NPB. The intrusion of the serpentinites might be either coeval or subsequent to the accretion of the oceanic crust onto the fore‐arc. Volcanogenic massive sulfide (VMS) deposits occur either in or near the contact between the pillow basalts and the overlying sediments or interbedded with the sediments. The morphology of the deposits, type of metals, ore texture and the nature of the host rocks suggest that the formation of the VMS bodies was similar to the accumulation of metals around and in the subsurface of hydrothermal vents observed in modern mid‐oceanic ridge and back‐arc basin rift settings. The podiform chromitites occur as pods and subordinate layers within totally serpentinized dunite in the residual upper mantle sequence. No large coherent chromitite deposit was found since the host dunitic rocks often occur as blocks within the serpentinites. It is difficult to evaluate the original geodynamic setting of the mineralized bodies since the chemistry of the host rocks were considerably modified by alteration during their tectonic emplacement. A preliminary conclusion for Antique is that the VMS is apparently associated with a primitive tholeiitic intermediate MORB‐IAB volcanic suite, the chemistry of which is close to the calculated composition of the liquid that coexisted with the podiform chromitites.  相似文献